Ζεόλιθοι υψηλής περιεκτικότητας σε Πυρίτιο

Μια γενική μέθοδος για την ενσωμάτωση Αλουμινίου σε Ζεόλιθους υψηλής περιεκτικότητας σε πυρίτιο με χρήση Φθοριούχου μέσου (General Method for Aluminum Incorporation into High-silica Zeolites Prepared in Fluoride Media)

Takahiko Moteki and Raul F. Lobo Chem. Mater., Just Accepted Manuscript DOI: 10.1021/acs.chemmater.5b04439 Publication Date (Web): December 17, 2015 Copyright © 2015 American Chemical Society Abstract The fluoride method of zeolite synthesis yields materials with unique characteristics such as high Si/Al ratio, large crystal size, and hydrophobic properties, and it has been advantageous for the synthesis of new pure-silica or high-silica zeolites. It is often difficult, however, to incorporate aluminum—and thus bring about useful catalytic properties—in materials prepared through the fluorite method. In this report we show that FAU-type zeolites are an effective source of aluminum to the growing crystals ... Διαβάστε περισσότερα